Highly accelerating effect of lewis acids on ruthenium(II)-catalyzed radical addition reactions.

نویسندگان

  • Shigeki Hoshimoto
  • Hirofumi Matsunaga
  • Masako Wada
  • Takehisa Kunieda
چکیده

The intramolecular ruthenium(II)-catalyzed radical addition of the trichloroacetyl pendant group to the 2-oxazolone skeleton is greatly enhanced in the presence of catalytic Lewis acids including rare earth metal triflates, thus providing a convenient route to a highly potential chiral synthon for vic-amino alcohols.

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عنوان ژورنال:
  • Chemical & pharmaceutical bulletin

دوره 50 3  شماره 

صفحات  -

تاریخ انتشار 2002